OK I get you want to add the Cust PO number to a grid... What grid? you can only add it to a SO or INV header grid.
and SO Header already has it.. so I'll assume you want to add it to the Shipments (INV_HIST_HDR)
Go into SU-A and bring up INV_HIST_HDR.
enter through the file name, then click on the Field data grid.
go to the bottom of the grid and press arrow down this will add a new record to the grid.
Type in Cust PO as a header.. enter
Then from the drop down for the field name select BKAR.INV.CUSORD ... enter
Then in the column Substr type in 3 (as 1 and 2 are used, you type in the next number up to 6 per grid)... enter
then save the grid.
You should be good to go.
also:
http://www.istechsupport.com/flash/editgrid.html